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methyl vinyl ketone : ウィキペディア英語版
methyl vinyl ketone

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Methyl vinyl ketone (MVK, IUPAC name: butenone) is the organic compound with the formula CH3C(O)CH=CH2. It is a reactive compound classified as an enone, in fact the simplest example thereof. It is a colorless, flammable, highly toxic liquid with a pungent odor. It is soluble in water and polar organic solvents. It is a useful intermediate in the synthesis of other compounds.〔
==Production==
MVK has been prepared industrially by the condensation of acetone and formaldehyde, followed by dehydration. Similarly it is prepared by the Mannich reaction involving diethylammonium chloride and acetone, which produces the Mannich adduct:
:CH3C(O)CH3 + CH2O + ()Cl → ()Cl
Heating this ammonium salt releases the ammonium chloride and the MVK:
:()Cl → [CH3C(O)CH=CH2 + [N(H)Et2]Cl

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